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Rhenium–Pyrazolyl-Based Figure-Eight- and Z-Shaped Metallocycles: Self-Assembly, Solid-State Structures, Dynamic Properties in Solution, and Competitive Ligand-Induced Supramolecular Transformations into Rhenium-Pyridyl/-Benzimidazolyl/-Phosphine-Based Metallocycles/Acyclic Complexes

[Image: see text] Rhenium(I)tricarbonyl core-based heteroleptic “figure-eight”- and Z-shaped metallocycles (1a–4a) of the general formula fac-[{(CO)(3)Re(μ-L)Re(CO)(3)}(2)(dppz)(2)] were self-assembled from Re(2)(CO)(10), H(2)-L (H(2)-L = 5,8-dihydroxy-1,4-naphthaquinone (H(2)-dhnq) for 1a; 1,4-dihy...

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Detalles Bibliográficos
Autores principales: Phukon, Upasana, Kedia, Moon, Shankar, Bhaskaran, Sathiyendiran, Malaichamy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10633831/
https://www.ncbi.nlm.nih.gov/pubmed/37969972
http://dx.doi.org/10.1021/acsomega.3c06371