Iridium-Catalyzed Enantioselective Alkene Hydroalkylation via a Heteroaryl-Directed Enolization–Decarboxylation Sequence

[Image: see text] Upon exposure to a cationic Ir(I)-complex modified with the chiral diphosphine DuanPhos, hydroalkylations of styrenes and α-olefins with diverse heteroaryl tert-butyl acetates occur with complete branched selectivity and very high enantioselectivity. The initial adducts undergo aci...

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Detalles Bibliográficos
Autores principales: Jing, Changcheng, Mao, Wenbin, Bower, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10636747/
https://www.ncbi.nlm.nih.gov/pubmed/37879082
http://dx.doi.org/10.1021/jacs.3c10163

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10636747/
https://www.ncbi.nlm.nih.gov/pubmed/37879082
http://dx.doi.org/10.1021/jacs.3c10163

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