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Photochemical halogen-bonding assisted carbothiophosphorylation reactions of alkenyl and 1,3-dienyl bromides

Herein, we present a synthetic procedure for the facile and general preparation of novel S-alkenyl and dienyl phosphoro(di)thioates for the first time. Extensive mechanistic investigations support that the reactions rely on a photochemical excitation of a halogen-bonding complex, formed with a phosp...

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Detalles Bibliográficos
Autores principales: Piedra, Helena F., Gebler, Victoria, Valdés, Carlos, Plaza, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10646874/
https://www.ncbi.nlm.nih.gov/pubmed/38020380
http://dx.doi.org/10.1039/d3sc05263j