Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe(3))(2)}(2) (E = Ge, Sn, Pb) and ECl{N(SiMe(3))(2)} (E = Ge, Sn)

Iconic Lappert's heavier tetrylenes E{N(SiMe(3))(2)}(2) (E = Ge (1), Sn (2), Pb (3)) have been efficiently prepared from GeCl(2)·(1,4-dioxane), SnCl(2) or PbCl(2) and Li{N(SiMe(3))(2)} via a completely solvent-free one-pot mechanochemical route followed by sublimation. This fast, high-yielding...

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Detalles Bibliográficos
Autores principales: Cabeza, Javier A., Reynes, Javier F., García, Felipe, García-Álvarez, Pablo, García-Soriano, Rubén
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10646885/
https://www.ncbi.nlm.nih.gov/pubmed/38020393
http://dx.doi.org/10.1039/d3sc02709k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10646885/
https://www.ncbi.nlm.nih.gov/pubmed/38020393
http://dx.doi.org/10.1039/d3sc02709k

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