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Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe(3))(2)}(2) (E = Ge, Sn, Pb) and ECl{N(SiMe(3))(2)} (E = Ge, Sn)
Iconic Lappert's heavier tetrylenes E{N(SiMe(3))(2)}(2) (E = Ge (1), Sn (2), Pb (3)) have been efficiently prepared from GeCl(2)·(1,4-dioxane), SnCl(2) or PbCl(2) and Li{N(SiMe(3))(2)} via a completely solvent-free one-pot mechanochemical route followed by sublimation. This fast, high-yielding...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10646885/ https://www.ncbi.nlm.nih.gov/pubmed/38020393 http://dx.doi.org/10.1039/d3sc02709k |