New insights into controlling radical migration pathways in heme enzymes gained from the study of a dye-decolorising peroxidase

In heme enzymes, such as members of the dye-decolorising peroxidase (DyP) family, the formation of the highly oxidising catalytic Fe(iv)-oxo intermediates following reaction with hydrogen peroxide can lead to free radical migration (hole hopping) from the heme to form cationic tyrosine and/or trypto...

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Detalles Bibliográficos
Autores principales: Lučić, Marina, Wilson, Michael T., Pullin, Jacob, Hough, Michael A., Svistunenko, Dimitri A., Worrall, Jonathan A. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10646903/
https://www.ncbi.nlm.nih.gov/pubmed/38020392
http://dx.doi.org/10.1039/d3sc04453j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10646903/
https://www.ncbi.nlm.nih.gov/pubmed/38020392
http://dx.doi.org/10.1039/d3sc04453j

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