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Hydration of Propargyl Esters Catalyzed by Gold(I) Complexes with Phosphoramidite Calix[4]pyrrole Cavitands as Ligands

[Image: see text] We report the synthesis and characterization of two diastereomeric phosphoramidite calix[4]pyrrole cavitands and their corresponding gold(I) complexes, 2(in)•Au(I)•Cl and 2(out)•Au(I)•Cl, featuring the metal center directed inward and outward with respect to their aromatic cavity....

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Detalles Bibliográficos
Autores principales: Sierra, Andrés F., Bulatov, Evgeny, Aragay, Gemma, Ballester, Pablo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10647111/
https://www.ncbi.nlm.nih.gov/pubmed/37918439
http://dx.doi.org/10.1021/acs.inorgchem.3c03089