(3+2)-Cycloadditions of Levoglucosenone (LGO) with Fluorinated Nitrile Imines Derived from Trifluoroacetonitrile: An Experimental and Computational Study †

The in situ-generated N-aryl nitrile imines derived from trifluoroacetonitrile smoothly undergo (3+2)-cycloadditions onto the enone fragment of the levoglucosenone molecule, yielding the corresponding, five-membered cycloadducts. In contrast to the ‘classic’ C(Ph),N(Ph) nitrile imine, reactions with...

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Detalles Bibliográficos
Autores principales: Mlostoń, Grzegorz, Urbaniak, Katarzyna, Palusiak, Marcin, Witczak, Zbigniew J., Würthwein, Ernst-Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10647924/
https://www.ncbi.nlm.nih.gov/pubmed/37959767
http://dx.doi.org/10.3390/molecules28217348

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10647924/
https://www.ncbi.nlm.nih.gov/pubmed/37959767
http://dx.doi.org/10.3390/molecules28217348

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