An Unusual Rearrangement of Pyrazole Nitrene and Coarctate Ring-Opening/Recyclization Cascade: Formal CH–Acetoxylation and Azide/Amine Conversion without External Oxidants and Reductants

We report an unusual transformation where the transient formation of a nitrene moiety initiates a sequence of steps leading to remote oxidative C–H functionalization (R–CH(3) to R–CH(2)OC(O)R’) and the concomitant reduction of the nitrene into an amino group. No external oxidants or reductants are n...

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Detalles Bibliográficos
Autores principales: Chugunova, Elena, Gazizov, Almir S., Islamov, Daut, Matveeva, Victoria, Burilov, Alexander, Akylbekov, Nurgali, Dobrynin, Alexey, Zhapparbergenov, Rakhmetulla, Appazov, Nurbol, Chabuka, Beauty K., Christopher, Kimberley, Tonkoglazova, Daria I., Alabugin, Igor V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10648078/
https://www.ncbi.nlm.nih.gov/pubmed/37959754
http://dx.doi.org/10.3390/molecules28217335

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10648078/
https://www.ncbi.nlm.nih.gov/pubmed/37959754
http://dx.doi.org/10.3390/molecules28217335

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