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C–H Bonds as Functional Groups: Simultaneous Generation of Multiple Stereocenters by Enantioselective Hydroxylation at Unactivated Tertiary C–H Bonds

[Image: see text] Enantioselective C–H oxidation is a standing chemical challenge foreseen as a powerful tool to transform readily available organic molecules into precious oxygenated building blocks. Here, we describe a catalytic enantioselective hydroxylation of tertiary C–H bonds in cyclohexane s...

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Detalles Bibliográficos
Autores principales: Palone, Andrea, Casadevall, Guillem, Ruiz-Barragan, Sergi, Call, Arnau, Osuna, Sílvia, Bietti, Massimo, Costas, Miquel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10651061/
https://www.ncbi.nlm.nih.gov/pubmed/37431886
http://dx.doi.org/10.1021/jacs.2c10148