Stereoselectivity control in Rh-catalyzed β-OH elimination for chiral allene formation

Stereoselectivity control and understanding in the metal-catalyzed reactions are fundamental issues in catalysis. Here we report sterically controlled rhodium-catalyzed S(N)2’-type substitution reactions of optically active tertiary propargylic alcohols with arylmetallic species affording the non-re...

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Detalles Bibliográficos
Autores principales: Wang, Jie, Zheng, Wei-Feng, Zhang, Xue, Qian, Hui, Ma, Shengming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10651921/
https://www.ncbi.nlm.nih.gov/pubmed/37968338
http://dx.doi.org/10.1038/s41467-023-42660-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10651921/
https://www.ncbi.nlm.nih.gov/pubmed/37968338
http://dx.doi.org/10.1038/s41467-023-42660-1

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