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Stereoselectivity control in Rh-catalyzed β-OH elimination for chiral allene formation
Stereoselectivity control and understanding in the metal-catalyzed reactions are fundamental issues in catalysis. Here we report sterically controlled rhodium-catalyzed S(N)2’-type substitution reactions of optically active tertiary propargylic alcohols with arylmetallic species affording the non-re...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10651921/ https://www.ncbi.nlm.nih.gov/pubmed/37968338 http://dx.doi.org/10.1038/s41467-023-42660-1 |