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Electronic origins of the stereochemistry in β-lactam formed through the Staudinger reaction catalyzed by a nucleophile
This paper evaluates the electronic effects of molecular substituents on the stereoselectivity of the umpolung Staudinger catalytic reaction. This is especially important because experimental studies on constructing the β-lactam ring, a core structure of most antibiotics, through catalyzed Staudinge...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10653035/ https://www.ncbi.nlm.nih.gov/pubmed/38020014 http://dx.doi.org/10.1039/d3ra05286a |