Examining the effects of additives and precursors on the reactivity of rhodium alkyl nitrenes generated from substituted hydroxylamines

In this study, the reactivity of the alkyl nitrenes, generated from the substituted hydroxylamine precursors, was determined using the same rhodium catalyst. The results revealed that in competitive C–H insertion experiments, the regioselectivity between benzylic and tertiary C–H bonds could be modu...

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Detalles Bibliográficos
Autores principales: Noda, Hidetoshi, Asada, Yasuko, Shibasaki, Masakatsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10654751/
https://www.ncbi.nlm.nih.gov/pubmed/38025067
http://dx.doi.org/10.3389/fchem.2023.1271896

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10654751/
https://www.ncbi.nlm.nih.gov/pubmed/38025067
http://dx.doi.org/10.3389/fchem.2023.1271896

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