A [CoSiH(2)] Silylene Synthon Provides Modular Access to Homo- and Heterobimetallic [Co=Si=M] (M = Co, Fe) Silicide Complexes

[Image: see text] Base-stabilized [BP(3)(iPr)](H)(2)CoSiH(2)(DMAP) (1, [BP(3)(iPr)] = PhB(CH(2)P(i)Pr(2))(3)(–); DMAP = 4-dimethylaminopyridine) is a rare instance of a synthon for the simplest “parent” silylene complex (LM=SiH(2)). Complex 1 was accessed in high yields via double Si–H bond activati...

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Detalles Bibliográficos
Autores principales: Handford, Rex C., Tilley, T. Don
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10655182/
https://www.ncbi.nlm.nih.gov/pubmed/37906296
http://dx.doi.org/10.1021/jacs.3c07998

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10655182/
https://www.ncbi.nlm.nih.gov/pubmed/37906296
http://dx.doi.org/10.1021/jacs.3c07998

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