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Delocalization quantitatively mapped for prototypic organic nitroanions as well as azidoform anions
Delocalization of occupied orbitals impacts the chemical bonding in the simplest known pernitroanions [(NO(2))(3)C](−) (1) and [(NO(2))(2)N](−) (2) as well as other functionalized organic anions. By quantitatively mapping it onto molecular backbones of 1, 2, [CH(2)NO(2)](−) (3), [CH(3)NNO(2)](−) (4)...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10655850/ https://www.ncbi.nlm.nih.gov/pubmed/38019983 http://dx.doi.org/10.1039/d3ra06708d |