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A ring of rotaxanes: studies of a large paramagnetic assembly in solution

Here we report the synthesis and structural characterization of four [7]rotaxanes formed by coordinating hybrid inorganic–organic [2]rotaxanes to a central {Ni(12)} core. X-ray single crystal diffraction demonstrate that [7]rotaxanes are formed, with a range of conformations in the crystal. Small an...

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Detalles Bibliográficos
Autores principales: Bennett, Tom S., Nawaz, Selina, Lockyer, Selena J., Asthana, Deepak, Whitehead, George F. S., Vitorica-Yrezabal, Inigo J., Timco, Grigore A., Burton, Neil A., Winpenny, Richard E. P., McInnes, Eric J. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10660382/
https://www.ncbi.nlm.nih.gov/pubmed/38021441
http://dx.doi.org/10.1039/d3qi02165c