Cargando…
A ring of rotaxanes: studies of a large paramagnetic assembly in solution
Here we report the synthesis and structural characterization of four [7]rotaxanes formed by coordinating hybrid inorganic–organic [2]rotaxanes to a central {Ni(12)} core. X-ray single crystal diffraction demonstrate that [7]rotaxanes are formed, with a range of conformations in the crystal. Small an...
Autores principales: | Bennett, Tom S., Nawaz, Selina, Lockyer, Selena J., Asthana, Deepak, Whitehead, George F. S., Vitorica-Yrezabal, Inigo J., Timco, Grigore A., Burton, Neil A., Winpenny, Richard E. P., McInnes, Eric J. L. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10660382/ https://www.ncbi.nlm.nih.gov/pubmed/38021441 http://dx.doi.org/10.1039/d3qi02165c |
Ejemplares similares
-
Conformational
Flexibility of Hybrid [3]- and [4]-Rotaxanes
por: Lockyer, Selena J., et al.
Publicado: (2020) -
Decorating polymer beads with 10(14) inorganic-organic [2]rotaxanes as shown by spin counting
por: Asthana, Deepak, et al.
Publicado: (2022) -
A [13]rotaxane assembled via a palladium molecular capsule
por: Ferrando-Soria, Jesus, et al.
Publicado: (2019) -
Close
Encounters of the Weak Kind: Investigations
of Electron–Electron Interactions between Dissimilar Spins
in Hybrid Rotaxanes
por: Lockyer, Selena J., et al.
Publicado: (2019) -
Disassembly Mechanisms
and Energetics of Polymetallic
Rings and Rotaxanes
por: Geue, Niklas, et al.
Publicado: (2022)