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Iterative Dual-Metal and Energy Transfer Catalysis Enables Stereodivergence in Alkyne Difunctionalization: Carboboration as Case Study

[Image: see text] Stereochemically defined tetrasubstituted olefins are widespread structural elements of organic molecules and key intermediates in organic synthesis. However, flexible methods enabling stereodivergent access to E and Z isomers of fully substituted alkenes from a common precursor re...

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Detalles Bibliográficos
Autores principales: Corpas, Javier, Gomez-Mendoza, Miguel, Arpa, Enrique M., de la Peña O'Shea, Víctor A., Durbeej, Bo, Carretero, Juan C., Mauleón, Pablo, Arrayás, Ramón Gómez
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10662505/
https://www.ncbi.nlm.nih.gov/pubmed/38026817
http://dx.doi.org/10.1021/acscatal.3c03570