Cargando…

Multiconfigurational photodynamics simulations reveal the mechanism of photodecarbonylations of cyclopropenones in explicit aqueous environments

Gas-evolving photochemical reactions use light and mild conditions to access strained organic compounds irreversibly. Cyclopropenones are a class of light-responsive molecules used in bioorthogonal photoclick reactions; their excited-state decarbonylation reaction mechanisms are misunderstood due to...

Descripción completa

Detalles Bibliográficos
Autores principales: Adrion, Daniel M., Karunaratne, Waruni V., Lopez, Steven A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664470/
https://www.ncbi.nlm.nih.gov/pubmed/38023495
http://dx.doi.org/10.1039/d3sc03805j