Photoswitchable and long-lived seven-membered cyclic singlet diradicals for the bioorthogonal photoclick reaction

Annularly 1,3-localized singlet diradicals are energetic and homolytic intermediates, but commonly too short-lived for widespread utilization. Herein, we describe a direct observation of a long-lived and seven-membered singlet diradical, oxepine-3,6-dione-2,7-diyl (OXPID), via spectroscopic experime...

Descripción completa

Detalles Bibliográficos
Autores principales: Hu, Fuqiang, Zhang, Cefei, Liu, Zhihao, Xie, Xinyu, Zhao, Xiaohu, Luo, Yanju, Fu, Jielin, Li, Baolin, Hu, Changwei, Su, Zhishan, Yu, Zhipeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664533/
https://www.ncbi.nlm.nih.gov/pubmed/38023496
http://dx.doi.org/10.1039/d3sc03675h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664533/
https://www.ncbi.nlm.nih.gov/pubmed/38023496
http://dx.doi.org/10.1039/d3sc03675h

Ejemplares similares