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The curious case of the crystalline tri-thorium cluster: cyclic delocalization without aromatic stabilization?
Actinides have been known to form extremely weak homonuclear bonds with their d-type orbitals, and one should therefore expect the superposition of cyclic resonance forms containing such bonds to bring rather marginal aromatic stabilization to the system, if any. It is for this very reason that the...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10664742/ https://www.ncbi.nlm.nih.gov/pubmed/38019979 http://dx.doi.org/10.1039/d3ra06603g |