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Nickel-catalyzed direct stereoselective α-allylation of ketones with non-conjugated dienes

The development of efficient and sustainable methods for the construction of carbon-carbon bonds with the simultaneous stereoselective generation of vicinal stereogenic centers is a longstanding goal in organic chemistry. Low-valent nickel(0) complexes which promote α-functionalization of carbonyls...

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Detalles Bibliográficos
Autores principales: Cao, Yi-Xuan, Wodrich, Matthew D., Cramer, Nicolai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10665391/
https://www.ncbi.nlm.nih.gov/pubmed/37993440
http://dx.doi.org/10.1038/s41467-023-43197-z