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Microscopic Evidence for the Topological Transition in Model Vitrimers

[Image: see text] In addition to the glass transition, vitrimers undergo a topological transition from viscoelastic liquid to viscoelastic solid behavior when the network rearrangements facilitated by dynamic bond exchange reactions freeze. The microscopic observation of this transition is elusive....

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Detalles Bibliográficos
Autores principales: Arbe, Arantxa, Alegría, Angel, Colmenero, Juan, Bhaumik, Saibal, Ntetsikas, Konstantinos, Hadjichristidis, Nikos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10666534/
https://www.ncbi.nlm.nih.gov/pubmed/37947419
http://dx.doi.org/10.1021/acsmacrolett.3c00586