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Crown-hydroxylamines are pH-dependent chelating N,O-ligands with a potential for aerobic oxidation catalysis

Despite the rich coordination chemistry, hydroxylamines are rarely used as ligands for transition metal coordination compounds. This is partially because of the instability of these complexes that undergo decomposition, disproportionation and oxidation processes involving the hydroxylamine motif. He...

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Detalles Bibliográficos
Autores principales: Lesnikov, Vladislav K., Golovanov, Ivan S., Nelyubina, Yulia V., Aksenova, Svetlana A., Sukhorukov, Alexey Yu.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10667252/
https://www.ncbi.nlm.nih.gov/pubmed/37996433
http://dx.doi.org/10.1038/s41467-023-43530-6