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When do tripdoublet states fluoresce? A theoretical study of copper(II) porphyrin

Open-shell molecules rarely fluoresce, due to their typically faster non-radiative relaxation rates compared to closed-shell ones. Even rarer is the fluorescence from states that have two more unpaired electrons than the open-shell ground state, since they involve excitations from closed-shell orbit...

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Detalles Bibliográficos
Autores principales: Wang, Xingwen, Wu, Chenyu, Wang, Zikuan, Liu, Wenjian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10667454/
https://www.ncbi.nlm.nih.gov/pubmed/38025061
http://dx.doi.org/10.3389/fchem.2023.1259016