A Convenient One-Pot Synthesis of a Sterically Demanding Aniline from Aryllithium Using Trimethylsilyl Azide, Conversion to β-Diketimines and Synthesis of a β-Diketiminate Magnesium Hydride Complex

This work reports the one-pot synthesis of sterically demanding aniline derivatives from aryllithium species utilising trimethylsilyl azide to introduce amine functionalities and conversions to new examples of a common N,N′-chelating ligand system. The reaction of TripLi (Trip = 2,4,6-iPr(3)-C(6)H(2...

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Detalles Bibliográficos
Autores principales: Demidov, Nikita, Grebogi, Mateus, Bourne, Connor, McKay, Aidan P., Cordes, David B., Stasch, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10673297/
https://www.ncbi.nlm.nih.gov/pubmed/38005290
http://dx.doi.org/10.3390/molecules28227569

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10673297/
https://www.ncbi.nlm.nih.gov/pubmed/38005290
http://dx.doi.org/10.3390/molecules28227569

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