Triplet bismuthinidenes featuring unprecedented giant and positive zero field splittings

Isolation of triplet pnictinidenes, which bear two unpaired electrons at the pnictogen centers, has long been a great challenge due to their intrinsic high reactivity. Herein, we report the syntheses and characterizations of two bismuthinidenes M(s)Fluind(t)(Bu)-Bi (3) and M(s)Fluind*-Bi (4) stabili...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Mengyuan, Chen, Wang, Wang, Dongmin, Chen, Yizhen, Ye, Shengfa, Tan, Gengwen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Oxford University Press 2023
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10684269/
https://www.ncbi.nlm.nih.gov/pubmed/38034397
http://dx.doi.org/10.1093/nsr/nwad169

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10684269/
https://www.ncbi.nlm.nih.gov/pubmed/38034397
http://dx.doi.org/10.1093/nsr/nwad169

Ejemplares similares