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Triplet bismuthinidenes featuring unprecedented giant and positive zero field splittings
Isolation of triplet pnictinidenes, which bear two unpaired electrons at the pnictogen centers, has long been a great challenge due to their intrinsic high reactivity. Herein, we report the syntheses and characterizations of two bismuthinidenes M(s)Fluind(t)(Bu)-Bi (3) and M(s)Fluind*-Bi (4) stabili...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Oxford University Press
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10684269/ https://www.ncbi.nlm.nih.gov/pubmed/38034397 http://dx.doi.org/10.1093/nsr/nwad169 |