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The first polyanion-substitution-driven centrosymmetric-to-noncentrosymmetric structural transformation realizing an excellent nonlinear optical supramolecule [Cd(4)P(2)][CdBr(4)]

Crystallographically, noncentrosymmetricity (NCS) is an essential precondition and foundation of achieving nonlinear optical (NLO), pyroelectric, ferroelectric, and piezoelectric materials. Herein, structurally, octahedral [SmCl(6)](3−) is substituted by the acentric tetrahedral polyanion [CdBr(4)](...

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Detalles Bibliográficos
Autores principales: Qiu, Zhi-Xin, Zheng, Zhe-Xiong, Jiang, Xiao-Ming, Liu, Bin-Wen, Guo, Guo-Cong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685307/
https://www.ncbi.nlm.nih.gov/pubmed/38033884
http://dx.doi.org/10.1039/d3sc04818g