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Isomerism tunes the diradical character of difluorenopyrroles at constant Hückel-level anti-aromaticity

A new diradical based on diindenocarbazole or difluorenopyrrole was synthesized and experimentally characterized by optical, electrochemical, and magnetic techniques, as well as quantum chemical calculations. The isomerism of these structures tunes the diradical character and the associated properti...

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Detalles Bibliográficos
Autores principales: Moriyasu, Ryotaro, Quintero, Sergio Moles, Gómez-García, Carlos J., Suzuki, Kazumasa, Kitamura, Chitoshi, Murata, Michihisa, Alonso, Mercedes, Casado, Juan, Kato, Shin-ichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685319/
https://www.ncbi.nlm.nih.gov/pubmed/38033889
http://dx.doi.org/10.1039/d3sc03297c