The magic of biaryl linkers: the electronic coupling through them defines the propensity for excited-state symmetry breaking in quadrupolar acceptor–donor–acceptor fluorophores

Charge transfer (CT) is key for molecular photonics, governing the optical properties of chromophores comprising electron-rich and electron-deficient components. In photoexcited dyes with an acceptor–donor–acceptor or donor–acceptor–donor architecture, CT breaks their quadrupolar symmetry and yields...

Descripción completa

Detalles Bibliográficos
Autores principales: Clark, John A., Kusy, Damian, Vakuliuk, Olena, Krzeszewski, Maciej, Kochanowski, Krzysztof J., Koszarna, Beata, O'Mari, Omar, Jacquemin, Denis, Gryko, Daniel T., Vullev, Valentine I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685337/
https://www.ncbi.nlm.nih.gov/pubmed/38033901
http://dx.doi.org/10.1039/d3sc03812b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685337/
https://www.ncbi.nlm.nih.gov/pubmed/38033901
http://dx.doi.org/10.1039/d3sc03812b

Ejemplares similares