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para-Selective dearomatization of phenols by I(i)/I(iii) catalysis-based fluorination

The regio- and enantio-selective dearomatization of phenols has been achieved by I(i)/I(iii) catalysis enabled fluorination. The process is highly para-selective, guiding the fluoride nucleophile to the distal C4 position of the substrate to generate fluorinated cyclohexadienones in an operationally...

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Detalles Bibliográficos
Autores principales: Stünkel, Timo, Siebold, Kathrin, Okumatsu, Daichi, Murata, Kazuki, Ruyet, Louise, Daniliuc, Constantin G., Gilmour, Ryan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685341/
https://www.ncbi.nlm.nih.gov/pubmed/38033893
http://dx.doi.org/10.1039/d3sc05952a