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para-Selective dearomatization of phenols by I(i)/I(iii) catalysis-based fluorination
The regio- and enantio-selective dearomatization of phenols has been achieved by I(i)/I(iii) catalysis enabled fluorination. The process is highly para-selective, guiding the fluoride nucleophile to the distal C4 position of the substrate to generate fluorinated cyclohexadienones in an operationally...
Autores principales: | Stünkel, Timo, Siebold, Kathrin, Okumatsu, Daichi, Murata, Kazuki, Ruyet, Louise, Daniliuc, Constantin G., Gilmour, Ryan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685341/ https://www.ncbi.nlm.nih.gov/pubmed/38033893 http://dx.doi.org/10.1039/d3sc05952a |
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