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Short, Scalable Access to Pyrrovobasine

[Image: see text] A concise gram-scale synthesis of pyrrovobasine (1) is reported. Key transformations include a three-step decagram-scale synthesis of the tetracyclic compound, Mn-mediated direct radical cyclization, and the introduction of a naturally rare pyrraline structure. The synthesis is des...

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Detalles Bibliográficos
Autores principales: Yu, Longhui, Nakamura, Hugh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685420/
https://www.ncbi.nlm.nih.gov/pubmed/38034961
http://dx.doi.org/10.1021/jacsau.3c00595