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Short, Scalable Access to Pyrrovobasine
[Image: see text] A concise gram-scale synthesis of pyrrovobasine (1) is reported. Key transformations include a three-step decagram-scale synthesis of the tetracyclic compound, Mn-mediated direct radical cyclization, and the introduction of a naturally rare pyrraline structure. The synthesis is des...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685420/ https://www.ncbi.nlm.nih.gov/pubmed/38034961 http://dx.doi.org/10.1021/jacsau.3c00595 |