Mechanistic Insights into Nitrile Activation by Cobalt(III)–Hydroperoxo Intermediates: The Influence of Ligand Basicity

[Image: see text] The versatile applications of nitrile have led to the widespread use of nitrile activation in the synthesis of pharmacologically and industrially valuable compounds. We reported the activation of nitriles using mononuclear cobalt(III)–hydroperoxo complexes, [Co(III)(Me(3)-TPADP)(O(...

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Detalles Bibliográficos
Autores principales: Son, Yeongjin, Jeong, Donghyun, Kim, Kyungmin, Cho, Jaeheung
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685436/
https://www.ncbi.nlm.nih.gov/pubmed/38034966
http://dx.doi.org/10.1021/jacsau.3c00532

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10685436/
https://www.ncbi.nlm.nih.gov/pubmed/38034966
http://dx.doi.org/10.1021/jacsau.3c00532

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