Cargando…

Dinitrogen cleavage by a dinuclear uranium(iii) complex

Understanding the role of multimetallic cooperativity and of alkali ion-binding in the second coordination sphere is important for the design of complexes that can promote dinitrogen (N(2)) cleavage and functionalization. Herein, we compare the reaction products and mechanism of N(2) reduction of th...

Descripción completa

Detalles Bibliográficos
Autores principales: Jori, Nadir, Keener, Megan, Rajeshkumar, Thayalan, Scopelliti, Rosario, Maron, Laurent, Mazzanti, Marinella
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10686047/
https://www.ncbi.nlm.nih.gov/pubmed/38033909
http://dx.doi.org/10.1039/d3sc05253b