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Dinitrogen cleavage by a dinuclear uranium(iii) complex
Understanding the role of multimetallic cooperativity and of alkali ion-binding in the second coordination sphere is important for the design of complexes that can promote dinitrogen (N(2)) cleavage and functionalization. Herein, we compare the reaction products and mechanism of N(2) reduction of th...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10686047/ https://www.ncbi.nlm.nih.gov/pubmed/38033909 http://dx.doi.org/10.1039/d3sc05253b |