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Cluster size dependent coordination of formate to free manganese oxide clusters

The interaction of free manganese oxide clusters, Mn(x)O(y)(+) (x = 1–9, y = 0–12), with formic acid was studied via infrared multiple-photon dissociation (IR-MPD) spectroscopy together with calculations using density functional theory (DFT). Clusters containing only one Mn atom, such as MnO(2)(+) a...

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Detalles Bibliográficos
Autores principales: Lang, Sandra M., Bernhardt, Thorsten M., Bakker, Joost M., Barnett, Robert N., Landman, Uzi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10686260/
https://www.ncbi.nlm.nih.gov/pubmed/37986571
http://dx.doi.org/10.1039/d3cp04035f