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sSPhos: A General Ligand for Enantioselective Arylative Phenol Dearomatization via Electrostatically-Directed Palladium Catalysis

[Image: see text] Arylative phenol dearomatization affords complex, cyclohexanone-based scaffolds from simple starting materials, and asymmetric versions allow access to valuable enantioenriched structures. However, bespoke chiral ligands must typically be identified for each new scaffold variation....

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Detalles Bibliográficos
Autores principales: Kadarauch, Max, Whalley, David M., Phipps, Robert J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10690801/
https://www.ncbi.nlm.nih.gov/pubmed/37972383
http://dx.doi.org/10.1021/jacs.3c10663