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pH Dependent Reversible Formation of a Binuclear Ni(2) Metal-Center Within a Peptide Scaffold
A disulfide-bridged peptide containing two Ni(2+) binding sites based on the nickel superoxide dismutase protein, {Ni(2)(SOD(mds))}, has been prepared. At physiological pH (7.4) it was found that the metal sites are mononuclear with a square planar NOS(2) coordination environment with the two sulfur...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10691859/ https://www.ncbi.nlm.nih.gov/pubmed/38046130 http://dx.doi.org/10.3390/inorganics7070090 |