Selective ring expansion and C−H functionalization of azulenes

We report a transition metal-catalyzed ring expansion of azulene that can be contrasted with C–H functionalization. This study represents the first example of the successful ring expansion of azulene using Cu(hfacac)(2) (hfacac: hexafluoroacetylacetonate) with a diazo reagent. This result is notable...

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Detalles Bibliográficos
Autores principales: Park, Sangjune, Kim, Cheol-Eui, Jeong, Jinhoon, Ryu, Ho, Maeng, Chanyoung, Kim, Dongwook, Baik, Mu-Hyun, Lee, Phil Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10692195/
https://www.ncbi.nlm.nih.gov/pubmed/38040685
http://dx.doi.org/10.1038/s41467-023-43200-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10692195/
https://www.ncbi.nlm.nih.gov/pubmed/38040685
http://dx.doi.org/10.1038/s41467-023-43200-7

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