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Selective ring expansion and C−H functionalization of azulenes

We report a transition metal-catalyzed ring expansion of azulene that can be contrasted with C–H functionalization. This study represents the first example of the successful ring expansion of azulene using Cu(hfacac)(2) (hfacac: hexafluoroacetylacetonate) with a diazo reagent. This result is notable...

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Detalles Bibliográficos
Autores principales:	Park, Sangjune, Kim, Cheol-Eui, Jeong, Jinhoon, Ryu, Ho, Maeng, Chanyoung, Kim, Dongwook, Baik, Mu-Hyun, Lee, Phil Ho
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10692195/ https://www.ncbi.nlm.nih.gov/pubmed/38040685 http://dx.doi.org/10.1038/s41467-023-43200-7

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