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Mechanistic manifold in a hemoprotein-catalyzed cyclopropanation reaction with diazoketone
Hemoproteins have recently emerged as promising biocatalysts for new-to-nature carbene transfer reactions. However, mechanistic understanding of the interplay between productive and unproductive pathways in these processes is limited. Using spectroscopic, structural, and computational methods, we in...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10693563/ https://www.ncbi.nlm.nih.gov/pubmed/38042860 http://dx.doi.org/10.1038/s41467-023-43559-7 |