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Investigation of acetyl migrations in furanosides

Standard reaction conditions for the desilylation of acetylated furanoside (riboside, arabinoside and xyloside) derivatives facilitate acyl migration. Conditions which favour intramolecular and intermolecular mechanisms have been identified with intermolecular transesterifications taking place under...

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Detalles Bibliográficos
Autores principales: Chevallier, O P, Migaud, M E
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2006
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1592296/
https://www.ncbi.nlm.nih.gov/pubmed/16859550
http://dx.doi.org/10.1186/1860-5397-2-14