Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation

An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS.

Detalles Bibliográficos
Autores principales: Nokami, Toshiki, Soma, Ryoji, Yamamoto, Yoshimasa, Kamei, Toshiyuki, Itami, Kenichiro, Yoshida, Jun-ichi
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Preliminary Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810300/
https://www.ncbi.nlm.nih.gov/pubmed/17288603
http://dx.doi.org/10.1186/1860-5397-3-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810300/
https://www.ncbi.nlm.nih.gov/pubmed/17288603
http://dx.doi.org/10.1186/1860-5397-3-7

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