Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation

An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS.

Detalles Bibliográficos
Autores principales: Nokami, Toshiki, Soma, Ryoji, Yamamoto, Yoshimasa, Kamei, Toshiyuki, Itami, Kenichiro, Yoshida, Jun-ichi
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Preliminary Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810300/
https://www.ncbi.nlm.nih.gov/pubmed/17288603
http://dx.doi.org/10.1186/1860-5397-3-7
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author Nokami, Toshiki
Soma, Ryoji
Yamamoto, Yoshimasa
Kamei, Toshiyuki
Itami, Kenichiro
Yoshida, Jun-ichi
author_facet Nokami, Toshiki
Soma, Ryoji
Yamamoto, Yoshimasa
Kamei, Toshiyuki
Itami, Kenichiro
Yoshida, Jun-ichi
author_sort Nokami, Toshiki
collection PubMed
description An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS.
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spelling pubmed-18103002007-03-06 Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation Nokami, Toshiki Soma, Ryoji Yamamoto, Yoshimasa Kamei, Toshiyuki Itami, Kenichiro Yoshida, Jun-ichi Beilstein J Org Chem Preliminary Communication An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS. Beilstein-Institut 2007-02-08 /pmc/articles/PMC1810300/ /pubmed/17288603 http://dx.doi.org/10.1186/1860-5397-3-7 Text en Copyright © 2007, Nokami et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Preliminary Communication
Nokami, Toshiki
Soma, Ryoji
Yamamoto, Yoshimasa
Kamei, Toshiyuki
Itami, Kenichiro
Yoshida, Jun-ichi
Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation
title Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation
title_full Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation
title_fullStr Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation
title_full_unstemmed Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation
title_short Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation
title_sort generation of pyridyl coordinated organosilicon cation pool by oxidative si-si bond dissociation
topic Preliminary Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810300/
https://www.ncbi.nlm.nih.gov/pubmed/17288603
http://dx.doi.org/10.1186/1860-5397-3-7
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AT yoshidajunichi generationofpyridylcoordinatedorganosiliconcationpoolbyoxidativesisibonddissociation

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