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Variations in product in reactions of naphthoquinone with primary amines

Reaction of 1,2-naphthoquinone with primary amines gives a 2-amino-1,4-naphthoquinone derivative which is equivalent to 1,2 to 1,4 carbonyl transposition. For example the reaction of 1,2-naphthoquinone with 4-methoxyaniline gives 2-(4-methoxyanilino)-naphthoquinone-1,4-(4-methoxyanil) (1) and with n...

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Detalles Bibliográficos
Autores principales: Singh, Marjit W, Karmakar, Anirban, Barooah, Nilotpal, Baruah, Jubaraj B
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1838918/
https://www.ncbi.nlm.nih.gov/pubmed/17331232
http://dx.doi.org/10.1186/1860-5397-3-10