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A Mononuclear and a Mixed-Valence Chain Polymer Arising from Copper(II) Halide Chemistry and the Use of 2,2′-Pyridil

Reactions of 2,2′-pyridil (pyCOCOpy) with CuCl(2) · 2H(2)O and CuBr(2) in EtOH yielded the mononuclear complex [Cu(pyCOOEt)(2)Cl(2)] · H(2)O (1) and the one-dimensional, mixed-valence complex [Cu(2) (I)Cu(II)(pyCOOEt)(2)Br(4)](n) (2), respectively. Both complexes crystallize in the triclinic space g...

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Detalles Bibliográficos
Autores principales: J. Milios, Constantinos, P. Raptopoulou, Catherine, Terzis, Aris, P. Perlepes, Spyros, S. Papaefstathiou, Giannis
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1939912/
https://www.ncbi.nlm.nih.gov/pubmed/18253464
http://dx.doi.org/10.1155/2007/28508