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A Mononuclear and a Mixed-Valence Chain Polymer Arising from Copper(II) Halide Chemistry and the Use of 2,2′-Pyridil
Reactions of 2,2′-pyridil (pyCOCOpy) with CuCl(2) · 2H(2)O and CuBr(2) in EtOH yielded the mononuclear complex [Cu(pyCOOEt)(2)Cl(2)] · H(2)O (1) and the one-dimensional, mixed-valence complex [Cu(2) (I)Cu(II)(pyCOOEt)(2)Br(4)](n) (2), respectively. Both complexes crystallize in the triclinic space g...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Hindawi Publishing Corporation
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1939912/ https://www.ncbi.nlm.nih.gov/pubmed/18253464 http://dx.doi.org/10.1155/2007/28508 |