Single and double stereoselective fluorination of (E)-allylsilanes

Acyclic allylic monofluorides were prepared by electrophilic fluorination of branched (E)-allylsilanes with Selectfluor. These reactions proceeded with efficient transfer of chirality from the silylated to the fluorinated stereocentre. Upon double fluorination, an unsymmetrical ethyl syn-2,5-difluor...

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Detalles Bibliográficos
Autores principales: Sawicki, Marcin, Kwok, Angela, Tredwell, Matthew, Gouverneur, Véronique
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Preliminary Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2151074/
https://www.ncbi.nlm.nih.gov/pubmed/17961218
http://dx.doi.org/10.1186/1860-5397-3-34

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2151074/
https://www.ncbi.nlm.nih.gov/pubmed/17961218
http://dx.doi.org/10.1186/1860-5397-3-34

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