Cargando…

Vinylogous Mukaiyama aldol reactions with 4-oxy-2-trimethylsilyloxypyrroles: relevance to castanospermine synthesis

BACKGROUND: The diastereoselectivity of a vinylogous Mukaiyama aldol reaction of a series of N-substituted 4-oxy-2-trimethylsilyloxypyrroles with a tartrate-based aldehyde has been explored as a model reaction for castanospermine synthesis. RESULTS: The study has revealed that the reaction is sensit...

Descripción completa

Detalles Bibliográficos
Autores principales: Hunter, Roger, Rees-Jones, Sophie C M, Su, Hong
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2151077/
https://www.ncbi.nlm.nih.gov/pubmed/17980041
http://dx.doi.org/10.1186/1860-5397-3-38